By Don S. Lemons
Striving to discover the topic in as easy a fashion as attainable, this booklet is helping readers comprehend the elusive notion of entropy. cutting edge facets of the publication comprise the development of statistical entropy from wanted houses, the derivation of the entropy of classical platforms from in simple terms classical assumptions, and a statistical thermodynamics method of the precise Fermi and excellent Bose gases. Derivations are labored via step by step and demanding purposes are highlighted in over 20 labored examples. round 50 end-of-chapter workouts try readers' realizing. The publication additionally encompasses a word list giving definitions for all crucial phrases, a time line exhibiting vital advancements, and checklist of books for extra learn. it truly is an excellent complement to undergraduate classes in physics, engineering, chemistry and mathematics.
Focuses on foundations and illustrative examples to assist readers comprehend the beginning and reasons of the concept that of entropy
Treats entropy throughout various issues, from thermodynamics, classical and quantum statistical mechanics, and data theory
Gives increased derivations, taking readers via each step-by-step
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Additional resources for A Student's Guide to Entropy
The physical content of the third law constrains the low temperature behavior of thermodynamic systems. Furthermore, Planck’s convention makes it possible to deine the absolute entropy of a system and so to produce tables of absolute entropies. The third law also has an interesting quantum statistical interpretation – a subject we take up in Chapter 4. An illustration Here we simply observe whether or not the entropy of various model systems obeys the third law of thermodynamics, that is, whether or not S → 0 as T → 0.
003 Cambridge Library Collection © Cambridge University Press, 2014 38 Statistical entropy Improbable macrostates The fundamental postulate implies that an isolated thermodynamic system moves probabilistically and without bias among all its possible microstates. But if so, a system may also move among sets of microstates that correspond to unusual macrostates, for instance, to air rushing to one corner of a room or to a cup of hot tea becoming yet hotter on a cold afternoon. We never observe such counter-intuitive macroscopic evolutions, not because they are impossible but rather because they are extremely improbable.
But if a model violates the third law of thermodynamics, we simply recognize its limited validity. For this reason the third law of thermodynamics is neither as foundational nor as consequential as the irst and second laws. Even so, the empirical content of the third law is invariably observed and cannot be derived from the other laws of thermodynamics. 7 The third law and blackbody radiation Problem: Determine whether or not the blackbody radiation equations of state obey the third law of thermodynamics.