Advances in Organometallic Chemistry, Vol. 12 by F.G.A. Stone, Robert West (Eds.)

By F.G.A. Stone, Robert West (Eds.)

ADVANCES ORGANOMETALLIC CHEMISTRY V12. content material: bankruptcy 7. The Literature of Organo-Transition steel Chemistry 1972Author Index: studies of Organo-Transition steel Chemistry; writer Index; topic Index; Cumulative checklist of individuals; Cumulative checklist of Titles. summary: ADVANCES ORGANOMETALLIC CHEMISTRY V12

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C. Effect of Alkyl and Aryl Groups . . . D. Effect of Ancillary Ligands . . . E. Effect of Solvent . . F. Intratriad Trends . . . . G. Comparison of Various Systems . . . H. Stereochemistry . . I. Mechanism . . . IV. Kinetics and Mechanism of Desulfination . V. Reactions of Sulfur Dioxide with u-Allyl, Propargyl, Cyclopropyl, and . Cyclopropylmethyl Complexes of Transition Metals A. Introduction. . . . . B. Metal-o-Ally1 Complexes . . C. Metal-Propargyl Complexes . . . D.

4. Structure of the product formed by the reaction of dicyclopentadiene with KIPtCl, in aqueous alcohols. They provided one of the first examples of the activation of a double bond to a relatively inert reagent (ROH) by coordination to a metal, and also showed that the first platinum(I1) a-bonded organo compounds were prepared as early as 1908 without, not surprisingly, their significance having been realized. , [PtClH(PR,),]. In the middle of the 1950s the only transition metal hydride complexes definitely identified were those containing carbon ligands in addition to the hydride ligand.

9) and (lo),, bears close analogy to the decarbonylation of metal-acyl complexes (137). In M--(SOa)-R M--(SOl)-R + SO1 + M-R - (9) ,SOP M; R some cases it is accompanied by loss of another ligand, L, such as a phosphine [Eqs. (11) and (12)] (15), thus suggesting that a vacant coordination position may be required for the fragmentation of RSO1. In general, elimination of SO, from transition metal sulfinates is not (S0nF-R + M-R + SO1 + L (1 1) M< L as common as elimination of CO from the corresponding acyls.

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